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The title complex, [Ni(C4H4O4S)(C3H4N2)3]·H2O, displays a distorted octa­hedral NiN3O2S coordination geometry, formed by three imidazole (imid) ligands and one thio­diacetate dianion. The NiII atom is displaced from one of the imid planes, and the angle between the corresponding Ni—N bond and the imid plane is 21.94 (19)°. This spatial orientation is stabilized by an inter­molecular C—H...π inter­action between one imid ligand and the C—H bond of an adjacent imid ligand.
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