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The title complex, [Ni(C7H3NO4)(C6H5N3)3], has been prepared hydro­thermally. Three neutral monodentate benzotriazole ligands occupy meridional sites about the octa­hedrally coordinated nickel(II) cation. The remaining sites are occupied by the N and two O atoms of a tridentate pyridine-2,6-dicarboxyl­ate dianion.

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The title compound, C7H7NO3S, is a simple new pyridylthio-N-oxide of pharmacological inter­est. There are two independent mol­ecules in the asymmetric unit. Strong O—H...O hydrogen-bond inter­actions link the mol­ecules in ribbons lying in the (101) plane.
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