metal-organic compounds
In the title complex, {[Ag(C9H8N4S2)(C2H3N)]BF4}n, the AgI atom shows trigonal–planar coordination, as it is coordinated by the N atoms from two bis(pyrimidin-2-ylsulfanyl)methane molecules and the N-atom donor of an acetonitrile molecule. The manner in which the donor molecules connect to the Ag atoms leads to a linear chain structure. Adjacent chains are connected into a layer via weak AgS interactions.
organic compounds
In the title compound, C14H14S2, there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the molecule adopts an anti conformation, with a planar -S-CH2-CH2-S- spacer unit. The dihedral angle between the phenyl ring and the S-C-C-S chain is 84.52 (18)°.