catena-Poly[[[(acetonitrile-κN)silver(I)]-μ-bis­(pyrimidin-2-ylsulfan­yl)methane-κ²N¹:N^1′] tetra­fluoro­borate]

In the title complex, {[Ag(C₉H₈N₄S₂)(C₂H₃N)]BF₄}_n, the Ag^I atom shows trigonal–planar coordination, as it is coordinated by the N atoms from two bis­(pyrimidin-2-ylsulfan­yl)methane mol­ecules and the N-atom donor of an acetonitrile mol­ecule. The manner in which the donor mol­ecules connect to the Ag atoms leads to a linear chain structure. Adjacent chains are connected into a layer via weak Ag...S inter­actions.

1,4-Bis(phenyl­sulfanyl)butane

The title compound, C₁₆H₁₈S₂, crystallizes with two half-mol­ecules in the asymmetric unit. In each independent mol­ecule, there is a centre of inversion at the mid-point of the central C-C bond. Each mol­ecule, excluding H atoms, is roughly planar and adopts an all-anti conformation. The dihedral angles between the phenyl rings and backbone chain are 19.5 (4) and 17.8 (4)°.

catena-Poly[[silver(I)-μ-1-phenyl­sulfanyl-2-(2-pyridylsulfan­yl)ethane-κ²S¹:N²] tetra­fluoro­borate]

In the title complex, {[Ag(C₁₃H₁₃NS₂)]BF₄}_n, the Ag^I ions show linear coordination through the N atom from one 1-phenyl­sulfanyl-2-(2-pyridylsulfan­yl)ethane (L) mol­ecule and the S atom of another. Each L ligand bridges two adjacent Ag atoms through the donor mol­ecules, leading to a linear chain structure.

1,2-Bis(phenyl­sulfan­yl)ethane

In the title compound, C₁₄H₁₄S₂, there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the mol­ecule adopts an anti conformation, with a planar -S-CH₂-CH₂-S- spacer unit. The dihedral angle between the phen­yl ring and the S-C-C-S chain is 84.52 (18)°.