metal-organic compounds
In the title complex, {[Ag(C9H8N4S2)(C2H3N)]BF4}n, the AgI atom shows trigonal–planar coordination, as it is coordinated by the N atoms from two bis(pyrimidin-2-ylsulfanyl)methane molecules and the N-atom donor of an acetonitrile molecule. The manner in which the donor molecules connect to the Ag atoms leads to a linear chain structure. Adjacent chains are connected into a layer via weak AgS interactions.