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In the title complex, {[Ag(C9H8N4S2)(C2H3N)]BF4}n, the AgI atom shows trigonal–planar coordination, as it is coordinated by the N atoms from two bis­(pyrimidin-2-ylsulfan­yl)methane mol­ecules and the N-atom donor of an acetonitrile mol­ecule. The manner in which the donor mol­ecules connect to the Ag atoms leads to a linear chain structure. Adjacent chains are connected into a layer via weak Ag...S inter­actions.
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