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In the title compound, C24H25N3O2S2, the piperidine ring adopts a distorted boat conformation. The phenyl rings subtend angles of 75.6 (1)° and 86.3 (1)° with the mean plane of the piperidine ring. In the crystal, mol­ecules are linked through a network C—H...N hydrogen bonds, forming zigzag chains along [100]. The thia­diazol ring methyl group is disordered over two positions with an occupancy ratio of 0.69 (4):0.31 (4).

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In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro­acetyl group is trans to the N atom of the diazepine ring. In the crystal, the mol­ecules form chains running along the diagonal of the ac plane through N—H...O hydrogen bonds.

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In the crystal of the title compound, C11H12O5S2, mol­ecules are linked by O—H...O hydrogen bonds and C—H...O inter­actions, forming a three-dimensional network.
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