organic compounds
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In the title compound, C22H17NO2, the acridine ring system and the benzene ring are oriented at a dihedral angle of 37.7 (1)°. The carboxyl group is twisted at an angle of 67.7 (1)° relative to the acridine skeleton. In the crystal, molecules are arranged in stacks along the b axis, with all of the acridine rings involved in multiple π–π interactions [centroid–centroid distances in the range 3.632 (2)–4.101 (2) Å]. The acridine moieties are parallel within the stacks, but inclined at an angle of 52.7 (1)° in adjacent stacks.
organic compounds
Open access
The acridine ring system and the benzene ring in the title compound, C20H13NO2, are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The molecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π–π interactions [centroid–centroid distances in the range 3.536 (2)–3.894 (2) Å]. Stacks arranged parallel are linked via C—Hπ interactions, forming layers in the ac plane that are in contact with adjacent, inversely oriented layers via other C—Hπ interactions, giving rise to double layers. The inversely oriented double layers interact dispersively. The acridine units are parallel within the parallel-oriented stacks, but inclined at an angle of 79.6 (2)° in the inversely oriented stacks.
organic compounds
Open access
In the title compound, C16H12O4, the substituent benzene ring and methoxy group are twisted relative to the 4H-chromene skeleton by 24.1 (1) and 61.3 (1)°, respectively. In the crystal, molecules are connected by classical O—HO and weak C—HO hydrogen bonds, forming chains parallel to [201]. The 4H-chromene ring systems of adjacent molecules are either parallel or inclined at an angle of 28.9 (1)°.