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The title compound, [Cu2(C2H3O2)2(C26H24P2)3]·2C4H10O, crystallizes with one dicopper(I) unit located on a centre of inversion and two diethyl ether mol­ecules in general positions. The Cu atoms exhibit slightly distorted tetra­hedral coordination.

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The title compound, C9H25N32+·2PF6-, consists of discrete hexa­fluoro­phosphate anions and 1,1,4,7,7-penta­methyl­diethylenetriamine cations. The geometric parameters are in the usual ranges. Only one PF6- cation forms hydrogen bonds with both NH donors of the cation.
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