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In the title salt hydrate, C2H10N22+·C12H10N2O62−·4H2O, each of the ions is located about a centre of inversion and the asymmetric unit is completed by two water molecules in general positons. In the crystal, the cations, anions and water mol­ecules are connected by O—H...O and N—H...O hydrogen bonding into a three-dimensional network.
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