A new mechanism of anionic substitution in fluoride borates

S. V. Rashchenko, T. B. Bekker, V. V. Bakakin, Y. V. Seryotkin, A. E. Kokh, P. Gille, A. I. Popov and P. P. Fedorov

A new mechanism of heterovalent anionic substitution was revealed in fluoride borates when a [(BO₃)F]⁴⁻ tetrahedral group is replaced by four fluoride anions. No exception to this mechanism has been discovered among all known phases with formal (BO₃)³⁻ ↔ 3F⁻ substitution.

Keywords: anionic isomorphism; fluoride borates; fluorine–fluorine interaction.

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