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4-Hy­droxy­pyridine and terephthalic acid cocrystallize as a hy­drate, 4-pyridone-terephthalic acid-water (2/1/2), 2C5H5NO·C8H6O4·2H2O, from a methanol-water solution. The mol­ecules form a two-dimensional hydrogen-bonded network resulting in sheets of hydrogen-bonded mol­ecules that lie parallel to the (10\overline 2) plane. In contrast, 3-hy­droxy­pyridine and terephthalic acid form the salt bis­(3-hy­droxy­pyridinium) terephthalate, 2C5H6NO+·C8H4O42-, giving rise to two-dimensional hydrogen-bonded sheets extending through the lattice parallel to the (10\overline 2) plane.
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