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In the title compound, C19H18F3NO4, which was designed and synthesized as a dual-site inhibitor of insect AChE (acetyl­cholinesterase), the dihedral angle between the methyl­carbamate group and the benzene ring is 72.47 (6)°. In the crystal, inversion dimers are linked by pairs of N—H...O hydrogen bonds.

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In the title compound, C8H9ClN2O, the dihedral angle between the benzene ring and the methyl­amide substituent is 68.39 (11)°. In the crystal, mol­ecules are linked by N—H...O hydrogen bonds, forming layers parallel to the ab plane.
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