metal-organic compounds
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The title compound, [Tb(NO3)3(C12H16N3O2)2], was prepared from the nitroxide radical ligand 4,4,5,5-tetramethyl-2-(pyridin-2-yl)-imidazoline-1-oxyl-3-oxide and TbIII nitrate. The TbIII ion adopts a doubly-capped square-antiprismatic coordination environment defined by three chelating nitrate anions and two N,O-bidentate nitronyl nitroxide radical ligands. Weak C—HO hydrogen bonds connect the molecules into a three-dimensional framework. The title structure is isotypic with the Ho analogue [Li (2012). Acta Cryst. E68, 550].