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The structure of title compound, C6H16N+·C14H8N3O7S, comprises discrete ions which are inter­connected by N—H...O and N—H+...O hydrogen bonds, leading to a neutral one-dimensional network along [100]. These hydrogen bonds appear to complement the Coulombic inter­action and help to stabilize the structure further.

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In the title disulfide, C12H8N6O2S2, all bond lengths and angles are within normal ranges, and the mol­ecules are linked into centrosymmetric R22(20) dimers by simple C-H...N inter­actions. Weak inter­molecular C-H...[pi](arene) and [pi]-[pi] inter­actions, involving the benzene CH groups and the benzene rings, and the pyridine rings, respectively, further stabilize and reinforce the crystal structure.
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