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In the title structure, C14H20NO3+·Cl, as expected, the pipiridine ring adopts a chair conformation and the carboxylic acid group and the benzene ring are essentially coplanar, forming a conjugated system. In the crystal structure, extended chains are formed through N—H...Cl and O—H...Cl hydrogen bonds.

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An E configuration is found about the C=C double bond in the title mol­ecule, C18H19NO3S. Evidence is found for significant conjugation in the C6H4-NMe2 residue.
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