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The title mol­ecule, [Co(C9H5O6)2(C12H8N2)] or [Co(H2BTC)2(phen)] (BTC = benzene-1,3,5-tricarboxyl­ate and phen = 1,10-phenanthroline), has crystallographic twofold symmetry. The CoII atom has a coordination geometry that is inter­mediate between octa­hedral and trigonal prismatic. In the crystal structure, mol­ecules are connected via O—H...O hydrogen bonds [O...O = 2.621 (4)–2.684 (4) Å] to form a three-dimensional network.
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