1-[(Z)-3-Ferrocenyl-1-(4-fluoro­phen­yl)-1-methoxy­prop-2-en-2-yl]-1H-1,2,4-triazole

The title compound, [Fe(C₅H₅)(C₁₇H₁₅FN₃O)], was synthesized unexpectedly during a search for potent fungicidal and plant growth regulatory agents. In the crystal structure, the mol­ecules form centrosymmetric dimers via weak inter­molecular C—H...F inter­actions. The planes of the substituted cyclo­penta­dienyl and benzene rings make dihedral angles of 93.9 (3) and 15.1 (2)°, respectively, with the triazole ring.

Diazido­bis(1,10-phenanthroline)cobalt(III) perchlorate

The title cobalt(III) complex, [Co(N₃)₂(C₁₂H₈N₂)₂]ClO₄, has been synthesized and structurally characterized. The complex cations have distorted octa­hedral geometry, formed by two chelating 1,10-phenanthroline ligands and two azide ligands in a cis configuration. The cations and anions lie on twofold rotation axes. The ions are linked together into a linear one-dimensional chain by hydrogen bonding.