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In the crystal structure of the title compound, [Cu(C10H8N2)2(H2O)4](ClO4)2·4C10H8N2, the asymmetric unit consists of one-half of a mononuclear [Cu(bpy)2(H2O)4]2+ cation (bpy is 4,4-bipyridine), one perchlorate ion and two solvent bpy mol­ecules, the formula unit being generated by crystallographic inversion symmetry. A three-dimensional network with triangular channels is formed via O—H...N hydrogen bonds and π–π inter­actions.
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