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In the title complex {alternative name: (2,2′-bipyridine-κ2N,N′)[3-(4-hydroxyphenyl)-2-(3-methoxy-2-oxidobenzylideneamino)propionato-κ3O,N,O′]oxovanadium(IV) methanol solvate monohydrate}, [V(C17H15NO5)O(C10H8N2)]·CH4O·H2O, the VIV atom is six-coordinated by three O atoms and three N atoms in a distorted octa­hedral configuration. In the crystal structure, the combination of intermolecular hydrogen-bonding (O—H...O) and π-stacking interactions creates a three-dimensional framework structure.
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