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In the crystal structure of the title two-dimensional complex, {[Cu(C8H4O5)(C5H6N2)2]·H2O}n, the Cu atom has a distorted square-pyramidal coordination geometry. As well as O—H...O hydrogen bonds within a two-dimensional layer, there are N—H...O hydrogen bonds which connect layers into a three-dimensional network. In addition, there are significant π–π stacking inter­actions between layers.
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