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In the structure of cobaltocenium trifluoro­methane­sulfonate [systematic name: bis­(η5-cyclo­penta­dien­yl)cobalt(III) tri­fluoro­methane­sulfonate], [Co(C5H5)2](CF3O3S) or [CoCp2][OTf], the asymmetric unit contains three independent anions, together with two full and two half-cations. Two of the cations reside on crystallographic inversion centers.
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