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In the title structure, C14H11N2O2Cl, the benzene rings are in a trans configuration with respect to the azo double bond and the mol­ecule is essentially planar.

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In the title structure, C16H16N2O3, the benzene rings are in a trans configuration with respect to the azo double bond and the mol­ecule is essentially planar.

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The title compound, C22H16N4O, displays a trans configuration with respect to the –N=N– double bond, as found for other diazene derivatives. There is a weak intra­molecular C—H...N hydrogen bond, which seems to have an effect on the mol­ecular conformation. The crystal packing is governed by weak inter­molecular C—H...N and C—H...O hydrogen bonds, and weak C—H...π stacking.
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