trans-Dichloro­bis[(phenyl­sulfan­yl)methane-κS]palladium(II)

The title compound, trans-[PdCl₂(PhSCH₂SPh)₂], crystallizes with two half-mol­ecules in the asymmetric unit and each independent mol­ecule lies about a crystallographic inversion center. In each mol­ecule, one S atom of the bis­(phenyl­sulfan­yl)methane ligand is coordinated to the Pd atom while the second S atom of the same ligand is uncoordinated.

1,10-Bis(phenyl­sulfanyl)decane

In the title structure, C₂₂H₃₀S₂, L¹⁰, the asymmetric unit contains two independent mol­ecules, both of which lie on crystallographic inversion centers, and the aliphatic chains are in the all-trans conformation. The crystal structure is stabilized by a combination of van der Waals forces and weak C—H...π(arene) inter­actions.

1,6-Bis(phenyl­sulfan­yl)hexa­ne

The title compound, C₁₆H₁₈S₂ (or L⁶), crystallizes with two half-mol­ecules in the asymmetric unit and each independent mol­ecule lies about a crystallographic center of symmetry. The aliphatic segment of this ligand is in an all-trans conformation.

1,2-Bis(phenyl­sulfanyl)ethane

In the title crystal structure, C₁₄H₁₄S₂, L², the mol­ecules lie on crystallographic inversion centers. The phen­yl rings are nearly perpendicular to the planar S-C-C-S group of atoms.