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The monomeric units in the title compound, C4H10Cl2NOP, are linked together by N—H...O hydrogen bonds to give parallel linear strands along the b axis.

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The title compound, 2-hydr­oxy-2-(4-hydroxy­phenyl)-N-methyl­ethanaminium chloride, C9H14NO2+·Cl, has been isolated for the first time from the genus Harrisonia. Its structure is stabilized by extensive intra- and inter­molecular hydrogen bonds of type O—H...O, N—H...O, N—H...Cl and C—H...Cl, resulting in a three-dimensional network. Additional weak π–π stacking inter­actions between adjacent mol­ecules further stabilize the crystal structure.
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