organic compounds
Open access
The structure of the monohydrate of α-4-(β-D-galactopyranosido)-D-glucopyranose, more commonly known as α-lactose monohydrate, C12H22O11·H2O, has been previously studied by single-crystal diffraction at ca 296 K [Beevers & Hansen (1971). Acta Cryst. B27, 1323–1325; Fries et al. (1971). Acta Cryst. B27, 994–1005; Noordik et al. (1984). Z. Kristallogr. 168, 59–65]. This redetermination at low temperature [150 (2) K] shows improved precision of geometry. Graph-set analysis of the hydrogen-bonding motifs is presented for the first time.