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In the title mol­ecule, C7H7N5O3S, all of the atoms in the fused ring system, except for the O atom, are essentially in the same plane. The O atom forms the flap of the envelope conformation of the sultone ring. In the absence of any hydrogen-bond or π–π stacking inter­actions, the structure appears to be stabilized only by normal van der Waals inter­actions.
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