metal-organic compounds
The title compound, [Ti2Cl(C6H9)(C12H14Si)2], displays an asymmetric μ2-η2 CC bridge between the two metal ions. The C—CC bond angle deviates markedly from linearity. The difference in the Ti—Cl bond lengths involving the bridging Cl is 0.146 (3) Å. The angles between the least-squares planes through the ring systems of the titanocene units are 55.4 (4) and 57.8 (4)°.