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The title compound, [Ti2Cl(C6H9)(C12H14Si)2], displays an asymmetric μ22 C[triple bond]C bridge between the two metal ions. The C—C[triple bond]C bond angle deviates markedly from linearity. The difference in the Ti—Cl bond lengths involving the bridging Cl is 0.146 (3) Å. The angles between the least-squares planes through the ring systems of the titanocene units are 55.4 (4) and 57.8 (4)°.
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