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The title compound, C18H18N4O2, was prepared from prop­yl chloro­formate and 3,6-diphen­yl-1,2-dihydro-1,2,4,5-tetra­zine. The central six-membered ring has a boat conformation. In the crystal structure, mol­ecules are linked via N—H...N [N...N = 3.015 (4) Å] and C—H...O [C...O = 3.265 (6) Å] hydrogen bonds to form extended chains along [100].
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