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The title compound, [Mo2(P2)(CO)4(C8H9O2)2], which was synthesized by refluxing a toluene solution of [(η5-CH3CH2O2CC5H4)2Mo2(CO)6] and P4 under N2, has a tetra­hedral [Mo2P2] core with a transverse coordinated P2 ligand and an [(η5-CH3CH2O2CC5H4)Mo(CO)2] moiety. The P—P distance of the coordinated P2 ligand is 2.089 (2) Å.
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