metal-organic compounds
The structure of the title compound, bis(μ-ferrocene-1,1′-diyl)bis[chloro(N,N,N′N′-tetramethylethylenediamine)aluminium], [Al2Fe2Cl2(C5H4)4(C6H16N2)2], possesses a center of inversion and an anti conformation. Bound to each Al atom in the bridging position are one Cl atom and one molecule of N,N,N′N′-tetramethylethylenediamine (TMEDA). The angle between the least-squares planes of the two cyclopentadienyl (Cp) ligands is 3.6 (3)°. The five C atoms in the Cp rings are staggered on average at an angle of 10.3 (5)°.
metal-organic compounds
The single-crystal X-ray analysis of the title compound, {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl}diiodoindium(III), [In(C14H28NSi3)I2], revealed monomeric molecules containing tetracoordinated In with an unusual trigonal-pyramidal geometry.