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The title compound, C23H20N2O4, is a soluble precursor (`latent pigment') of diketopyrrolo­pyrrole pigments. The tert-butoxy­carbonyl group is twisted by 78.5 (1)° with respect to the heterocyclic ring system. In the crystal structure, pairs of mol­ecules form centrosymmetric dimers through N—H...O intermolecular hydrogen bonds and are stacked in a herring-bone fashion along the a axis.

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In the title compound, C24H12N4O4·2C3H7NO, the naphthalene imide, which is an organic pigment utilized for H2 gas sensors, has inversion symmetry. The pyridyl rings are twisted, in the same direction, out of the plane of the naphthalene imide skeleton by 69.5 (2)°.
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