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In the title salt, C20H21N{}_{2}^{+}·C7H7SO{}_{3}^{- }·H2O, the quinolinium cation exhibits a large molecular non-linear optical (NLO) response, as determined by Stark spectroscopy, but crystallization in the centrosymmetric space group P\overline{1} precludes significant bulk NLO effects. Intermolecular O—H...O and weak C—H...O hydrogen bonding links the constituent mol­ecules into a three-dimensional network.
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