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The title compound, C10H8N2O4S, serves as a starting material for the synthesis of antihyperglycemic pharmaceuticals. The nearly planar thia­zolidine-2,4-dione ring is almost perpendic­ular to the nitro­phenyl ring.

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The title compound, C8H7NO2, serves as an intermediate for the synthesis of citalopram. The packing of the planar mol­ecules is stabilized by N—H...O and N—H...N hydrogen bonds.

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The title compound, C8H5BrO2, serves as a starting material for the synthesis of citalopram. It crystallizes with two almost identical mol­ecules in the asymmetric unit.

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The title compound, C9H13NO, is the key intermediate for the synthesis of the antidiabetic drug pioglitazone and it is used as a versatile intermediate in the synthesis of a number of biologically active novel heterocycles. Both side-chains are located on the same side of the aromatic ring. The mol­ecules are connected by O—H...N hydrogen bonds into ribbons which show a herring-bone-like pattern.

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The title compound, C12H12BrNO4S, belongs to the class of substituted thia­zolidine-2,4-diones. Compounds of this type are important starting materials in pharmaceutical chemistry. The thia­zolidine-2,4-dione ring is disordered about a twofold rotation axis. Geometric parameters, other than those of the disordered groups, are in the normal ranges.

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The title compound, C16H18N2O2, is a key intermediate for the synthesis of biologically active novel heterocycles, e.g. isoxazolines and isoxazoles. Geometric parameters of the mol­ecule are in the usual ranges. The crystal packing is stabilized by an O—H...N hydrogen bond.

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The title compound, C33H25BrN4, belongs to the class of substituted tetrazoles. This type of compound is an important starting material for the synthesis of pharmaceutically active materials.
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