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The structure of the title compound, C9H10O4, is presented and compared with 4-hydroxy-3,5-di­methoxy­benz­aldehyde. Both form infinite hydrogen-bonded chains.

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The ethene units of the title compound, C32H24S, a possible candidate for Organic Light-Emitting Devices, are tilted with respect to the thio­phene unit by 6.2 (1) and 9.2 (1)°.
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