metal-organic compounds
The crystal structure of the title complex, (C8H10NO2)[Ni(dmit)2] (dmit is 4,5-dimercapto-1,3-dithiole-2-thione, C3H2S5), is characterized by its two-dimensional SS intermolecular interactions and can be described as an arrangement of quasi-planar [Ni(dmit)2]− anions, separated by cation pairs. Centrosymmetric cation pairs are formed through weak C—HO hydrogen bonds (HO = 2.23 Å).