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The crystal structure of the title complex, (C8H10NO2)[Ni(dmit)2] (dmit is 4,5-dimercapto-1,3-di­thiole-2-thione, C3H2S5), is characterized by its two-dimensional S...S intermolecular interactions and can be described as an arrangement of quasi-planar [Ni(dmit)2] anions, separated by cation pairs. Centrosymmetric cation pairs are formed through weak C—H...O hydrogen bonds (H...O = 2.23 Å).
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