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In the title compound, C10H6N4O5S, the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0294 Å] forms dihedral angles of 12.48 (7) and 46.66 (9)° with the planes of the thiazole and benzene rings, respectively. In the crystal, molecules are linked by N—HO hydrogen bonds, forming chains along [001]. In addition, weak C—HO hydrogen bonds link these chains, forming a two-dimensional network, containing R44(28) ring motifs parallel to (100).