metal-organic compounds
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In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)2]·CH3OH, the AgI ion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent molecules are linked by O—HO and N—HO hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C—HO hydrogen bonds forming a two-dimensional supramolecular architecture parallel to (001). In addition, an intramolecular N—HO hydrogen bond is observed.