organic compounds
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The asymmetric unit of the title salt, 2C6H5CH2NH3+·H2P2O72−, contains two independent benzylammonium cations and a dihydrogen diphosphate dianion. In the crystal, O—HO and N—HO hydrogen bonds link the cations and anions, forming a two-dimensional network parallel to (010). Within this network, weak C—HO hydrogen bonds are observed.