Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­pentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ²N¹,N¹¹)rhenium(I)

In the title compound, [ReCl(C₁₅H₁₆N₄)(CO)₃], the Re^I ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H...Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).

Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ²N¹,N¹¹)rhenium(I)

In the title compound, [ReCl(C₁₆H₁₈N₄)(CO)₃], the Re^I ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N—H...Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (100).