2-Hy­droxy-N′-methyl-5-nitro­benzohydrazide

In the title compound, C₈H₉N₃O₄, there are two mol­ecules in the asymmetric unit, one of which is in the zwitterionic form. The zwitterion contains an intra­molecular N—H...O hydrogen bond and the other mol­ecule contains both an intra­molecular N—H...O and an intra­molecular O—H...O hydrogen bond. In the crystal, N—H...O and N—H...N hydrogen bonds link the mol­ecules, formimg a two-dimensional network parallel to (10-1).

Epibisde­hydro­neotuberostemonine J

The title compound, C₂₂H₂₉NO₄, a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a twist-chair conformation due to fusion with pyrrole ring C while ring D adopts a chair conformation. The junction between rings A and B is cis. In the crystal, weak C—H...O inter­actions involving the two carbonyl groups, a methyl­ene and a methyl group give rise to a three-dimensional network.