metal-organic compounds
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In the title compound, [Ni(C5H4N3O2)2(H2O)2]·2H2O, the NiII ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—HO, N—HO and O—HN hydrogen bonds involving the solvent water molecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—HO, N—HO and C—HO hydrogen bonds involving the axial aqua ligands, amino groups and the carboxylate groups of the APZC ligands, forming a three-dimensional network.