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The asymmetric unit of the title compound, C26H18N6O4S, contains two independent molecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in molecules A and B, respectively. The dihedral angles between the pyridine and benzene rings in A and B are 65.53 (13 )and 87.67 (13) Å, respectively. In the crystal, molecules A and B are linked through a pair of N—H
N hydrogen bonds involving one -NH2 group H atom and second pair of N—HN hydrogen bonds involving the other -NH2 group H atom, forming an –ABAB– ribbon along [100] containing R22(8) and R22(12) ring motifs. These ribbons are further connected by weak C—HN, C—HO and C—Hπ interactions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1).
N hydrogen bonds involving one -NH2 group H atom and second pair of N—HN hydrogen bonds involving the other -NH2 group H atom, forming an –ABAB– ribbon along [100] containing R22(8) and R22(12) ring motifs. These ribbons are further connected by weak C—HN, C—HO and C—Hπ interactions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1).organic compoundsOpen access
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In the title compound, C15H12FN3O2, the dihedral angles between the central benzene ring and the pendant benzene and oxadiazole rings are 45.05 (13) and 15.60 (14)°, respectively. The C atom of the methoxy group is roughly coplanar with its attached ring [displacement = 0.178 (4) Å]. In the crystal, N—HN hydrogen bonds link the molecules into [010] chains. Weak C—Hπ interactions are also observed.
N hydrogen bonds link the molecules into [010] chains. Weak C—Hπ interactions are also observed.organic compoundsOpen access
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In the title compound, C7H8N6O2S, the dihedral angle between the imidazole and thiadiazole rings is 70.86 (15)°. In the crystal, molecules are linked into [10-1] chains by N—HN hydrogen bonds, which incorporate centrosymmetric R22(8) and R22(18) loops. The chains are linked by C—HO and C—HN interactions, generating a three-dimensional network. Very weak π–π stacking [centroid–centroid distance = 3.901 (17) Å] is also observed.
N hydrogen bonds, which incorporate centrosymmetric R22(8) and R22(18) loops. The chains are linked by C—HO and C—HN interactions, generating a three-dimensional network. Very weak π–π stacking [centroid–centroid distance = 3.901 (17) Å] is also observed.
