organic compounds
Open access
In the title molecule, C24H28N2O3, the cyclohexene ring is in a sofa conformation and the 1,4-dihydropyridine ring is in a slight boat conformation. In the indole ring system, the pyrrole and benzene rings form a dihedral angle of 2.63 (7)°. In the crystal, N—HO hydrogen bonds connect the molecules into C(6) chains parallel to the b axis and pairs of weak C—HO hydrogen bonds link inversion-related chains into a ladder motif through R22(18) rings. A weak intramolecular C—HO hydrogen bond is also observed.
organic compounds
Open access
The whole molecule of the title compound, C17H21NO2, is generated by twofold rotational symmetry. The N atom and the C and H atoms in position 4 of the pyridine ring lie on the twofold axis. The cyclohexene ring has a sofa conformation with the CH2 C atom adjacent to the dimethyl-substituted C atom displaced by 0.5949 (16) Å from the mean plane of the other five C atoms. In the crystal, weak C—HO interactions link the molecules into chains parallel to the a axis. In addition, π–π stacking interactions [centroid–centroid distance = 3.8444 (7) Å] contribute to the stabilization of the crystal structure.