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In the title mol­ecule, C12H12N4O3S, there is an intra­molecular O—H...N hydrogen bond. The dihedral angle between the benzene and triazine rings is 65.9 (3)°. In the crystal, N—H...S and O—H...N hydrogen bonds link the mol­ecules into chains along [010]. In addition, there are weak π–π stacking inter­actions between symmetry-related triazine rings with a centroid–centroid distance of 3.560 (3)°.
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