N-(3-Amino­bicyclo­[2.2.1]heptan-2-yl)-4-methyl­benzene­sulfonamide

In the title compound, C₁₄H₂₀N₂O₂S, the sulfonamide O atoms lie to one side of the benzene ring and the amino­bicyclo­hepta­nyl to the other side [C_ar—S—N—C torsion angle = −57.93 (11)°; ar = aromatic]. An intra­molecular N—H...N hydrogen bond is formed. In the crystal, a supra­molecular chain is formed along the b axis via N—H...O and N—H...N hydrogen bonds.

(11R,12S)-16-Amino­tetra­cyclo­[6.6.2.0^2,7.0^9,14]hexa­deca-2(7),3,5,9(14),10,12-hexaen-15-ol

In the title compound, C₁₆H₁₅NO, the dihedral angle between the outer benzene rings is 51.88 (6)°, and each of the central six-membered rings has a boat conformation. The hy­droxy and amino groups are syn, and the hy­droxy H atom forms an intra­molecular O—H...N hydrogen bond. In the crystal, mol­ecules assemble via C—H...O and C—H...π inter­actions, consolidating a three-dimensional architecture.