metal-organic compounds
Open access
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ2N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
In the title compound, [Cd2I4(C6H14N2)2]n, there are two independent CdII ions. One CdII ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other CdII ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment. Two of the iodido ligands act as bridging ligands connecting CdII ions and forming a one-dimensional polymer along [010]. In the crystal, N—HI hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001).
organic compounds
Open access
In the title molecule, C17H11Cl2N3O, the C=C bond connecting the triazole and 4-chlorophenyl groups adopts a Z geometry. The dihedral angles formed by the triazole ring and the 4-chloro substituted benzene rings are 67.3 (1) and 59.1 (1)°. The dihedral angle between the two benzene rings is 73.5 (1)°.