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In the title mol­ecule, C14H22N6O4, the amide-substituted N atoms of the tetra­zine ring deviate from the approximate plane of the four other atoms in the ring by 0.160 (2) and 0.243 (2) Å, forming a slight boat conformation. The morpholine rings are in chair conformations.

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In the title mol­ecule, C16H16N8O2, four atoms of the tetra­zine ring are coplanar, with the largest deviation from the plane being 0.0236 (12) Å; the other two atoms of the tetra­zine ring deviate on the same side from this plane by 0.320 (4) and 0.335 (4) Å. Therefore, the central tetra­zine ring exhibits a boat conformation. The dihedral angles between the mean plane of the four coplanar atoms of the tetrazine ring and the two pyridine rings are 26.22 (10) and 6.97 (5)°. The two pyridine rings form a dihedral angle of 31.27 (8)°. In the molecule, there are a number of short C—H...O interactions. In the crystal, molecules are linked via a C—H...O interaction to form zigzag chains propagating along the [010] direction.
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