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In the title compound, [Ni(C21H24N2O2)]·H2O, both the complex mol­ecule and the water mol­ecule lie on a twofold rotation axis. The NiII ion is coordinated in a distorted square-planar geometry by the tetra­dentate ligand. The dihedral angle between the two symmetry-related benzene rings is 47.12 (8)°. In the crystal, pairs of symmetry-related O—H...O hydrogen bonds form R22(6) ring motifs. In addition, there are weak inter­molecular C—H...O hydrogen bonds, and π–π stacking inter­actions with a centroid–centroid distance of 3.4760 (8) Å.
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