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In the title mol­ecule, C13H15ClF2N2O, the piperazine ring is in a chair conformation with the 2,4-difluoro­benzyl and chloro­acetyl substituents in equatorial positions.

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In the title molecular salt, C2H4N3+·C7H5Cl2O3S, C—C—S angle [112.25 (18)°] deviates slightly from that expected for ideal sp3-hybridization geometry. In the crystal, the components are linked by N—H...O and bifurcated N—H...(O,O) hydrogen bonds into chains parallel to [110].
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