organic compounds
Open access
The title compound, C9H8N3O+·Cl−, was isolated from a liquid culture of streptomyces sp. In the cation, the ring system makes a dihedral angle of 0.2 (2)° with the amide group. The protonation creating the cation occurs at ome of the N atoms in the quinoxaline ring system. In the crystal, the ions are linked through N—HO and N—HCl hydrogen bonds, forming a two-dimensional network parallel to (10).
organic compounds
Open access
The structure of the title compound, C14H13BrO2, which contains a norbornenyl group and a 4-bromobenzoate ester at the single C-atom bridge, has been redetermined [see McDonald & Trotter (1965). Acta Cryst. 19, 456-463] to modern standards to establish high-precision geometrical data to compare with norbornyl and other tetracyclic 4-bromobenzoates. Possible structural evidence is sought to help explain solvolytic reactivities.
organic compounds
Open access
The title compound, C14H15BrO2, contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxylate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxylate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, molecules pack as pairs of enantiomers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings.